Can simple particle shapes be used to model scalar optical properties of an ensemble of wavelength-sized particles with complex shapes?

We compute the scalar optical properties of size-shape distributions of wavelength-sized randomly oriented homogeneous particles with different nonaxially symmetric geometries and investigate how well they can be modeled with a simple spherical, spheroidal, or cylindrical particle model. We find that a spherical particle model can be used to determine the extinction and scattering cross sections, the single-scattering albedo, and the asymmetry parameter with an error of less than 2%, whereas the extinction-to-backscatter ratio R-eb is reproduced only with an error of 9%. The cylindrical and spheroidal particle models yield slightly improved results for R-eb that deviate from those obtained for the complex particle ensemble by 7% and 5%, respectively. Large discrepancies between results of the different models are observed for the linear depolarization ratio, thus indicating limitations of models based on simple particle shapes. (C) 2002 Optical Society of America.