Exceptionally high Felkin-Anh control for the addition of nucleophiles to a beta-aminocyclopropylcarbaldehyde

被引：14

作者：

Bubert, C

Reiser, O

机构：

[1] UNIV STUTTGART,INST ORGAN CHEM,D-70569 STUTTGART,GERMANY

[2] UNIV GOTTINGEN,INST ORGAN CHEM,D-37077 GOTTINGEN,GERMANY

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 28期

关键词：

D O I：

10.1016/S0040-4039(97)01065-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Exceptionally high diastereocontrol in agreement with the Felkin-Anh model was observed for the addition of nucleophiles to the beta-aminocyclopropylcarbaldehyde 5 in nitroaldol, cyanohydrin, Mukaiyama aldol, and Sakurai reactions, contrasting the low diastereoselectivities generally observed in additions to cyclopropylcarbaldehydes. (C) 1997 Elsevier Science Ltd.

引用

页码：4985 / 4988

页数：4

共 25 条

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