Synthesis of generational polyester dendrimers derived from glycerol and succinic or adipic acid

被引：60

作者：

Carnahan, MA

Grinstaff, MW ^{[1
]}

机构：

[1] Boston Univ, Dept Chem, Boston, MA 02215 USA

[2] Boston Univ, Dept Biomed Engn, Boston, MA 02215 USA

来源：

MACROMOLECULES | 2006年 / 39卷 / 02期

关键词：

D O I：

10.1021/ma0518407

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The divergent syntheses of dendrimers composed of glycerol and varying layers of succinic and adipic acids are described. These alternating and bilayer generational copolymers are prepared in high yield using sequential esterification and hydrogenolysis reactions. The glass transition temperatures and solubilities are dependent on the composition of the outer generation layer.

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页码：609 / 616

页数：8

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