Microporous Carbon Nanoplates from Regenerated Silk Proteins for Supercapacitors

被引:516
作者
Yun, Young Soo [1 ]
Cho, Se Youn [1 ]
Shim, Jinyong [2 ]
Kim, Byung Hoon [3 ]
Chang, Sung-Jin [4 ]
Baek, Seung Jae [5 ,6 ]
Huh, Yun Suk [7 ]
Tak, Yongsug [2 ]
Park, Yung Woo [5 ,6 ]
Park, Sungjin [8 ]
Jin, Hyoung-Joon [1 ]
机构
[1] Inha Univ, Dept Polymer Sci & Engn, Inchon 402751, South Korea
[2] Inha Univ, Dept Chem Engn, Inchon 402751, South Korea
[3] Univ Incheon, Dept Phys, Inchon 406772, South Korea
[4] Korea Basic Sci Inst KBSI, Div Mat Sci, Taejon 305333, South Korea
[5] Seoul Natl Univ, Dept Phys & Astron, Seoul 151747, South Korea
[6] Seoul Natl Univ, Dept Nano Sci & Technol, Seoul 151747, South Korea
[7] Inha Univ, Dept Biol Engn, Inchon 402751, South Korea
[8] Inha Univ, Dept Chem, Inchon 402751, South Korea
基金
新加坡国家研究基金会;
关键词
supercapacitor; pseudocapacitance; carborn nanoplate; carbonization; silk; ELECTROCHEMICAL CAPACITORS; HIGH-POWER; NITROGEN; GRAPHENE; PERFORMANCE; ENERGY; FILMS; ACTIVATION; MECHANISM; ELECTRODES;
D O I
10.1002/adma.201204692
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Novel carbon-based microporous nanoplates containing numerous heteroatoms (H-CMNs) are fabricated from regenerated silk fibroin by the carbonization and activation of KOH. The H-CMNs exhibit superior electrochemical performance, displaying a specific capacitance of 264 F/g in aqueous electrolytes, a specific energy of 133 Wh/kg, a specific power of 217 kW/kg, and a stable cycle life over 10000 cycles.
引用
收藏
页码:1993 / 1998
页数:6
相关论文
共 33 条
[1]  
An KH, 2001, ADV FUNCT MATER, V11, P387, DOI 10.1002/1616-3028(200110)11:5<387::AID-ADFM387>3.0.CO
[2]  
2-G
[3]   CARBON FIBRE FORMATION - OXIDATION TREATMENT [J].
BAILEY, JE ;
CLARKE, AJ .
NATURE, 1971, 234 (5331) :529-&
[4]   Graphene Oxide-MnO2 Nanocomposites for Supercapacitors [J].
Chen, Sheng ;
Zhu, Junwu ;
Wu, Xiaodong ;
Han, Qiaofeng ;
Wang, Xin .
ACS NANO, 2010, 4 (05) :2822-2830
[5]  
Chmiola J, 2006, SCIENCE, V313, P1760, DOI 10.1126/science/1132195
[6]   Desolvation of ions in subnanometer pores and its effect on capacitance and double-layer theory [J].
Chmiola, John ;
Largeot, Celine ;
Taberna, Pierre-Louis ;
Simon, Patrice ;
Gogotsi, Yury .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (18) :3392-3395
[7]   High power density supercapacitor electrodes of carbon nanotube films by electrophoretic deposition [J].
Du, Chunsheng ;
Pan, Ning .
NANOTECHNOLOGY, 2006, 17 (21) :5314-5318
[8]   Carbon materials for the electrochemical storage of energy in capacitors [J].
Frackowiak, E ;
Béguin, F .
CARBON, 2001, 39 (06) :937-950
[9]   High-yield production of graphene by liquid-phase exfoliation of graphite [J].
Hernandez, Yenny ;
Nicolosi, Valeria ;
Lotya, Mustafa ;
Blighe, Fiona M. ;
Sun, Zhenyu ;
De, Sukanta ;
McGovern, I. T. ;
Holland, Brendan ;
Byrne, Michele ;
Gun'ko, Yurii K. ;
Boland, John J. ;
Niraj, Peter ;
Duesberg, Georg ;
Krishnamurthy, Satheesh ;
Goodhue, Robbie ;
Hutchison, John ;
Scardaci, Vittorio ;
Ferrari, Andrea C. ;
Coleman, Jonathan N. .
NATURE NANOTECHNOLOGY, 2008, 3 (09) :563-568
[10]   Combined Effect of Nitrogen- and Oxygen-Containing Functional Groups of Microporous Activated Carbon on its Electrochemical Performance in Supercapacitors [J].
Hulicova-Jurcakova, Denisa ;
Seredych, Mykola ;
Lu, Gao Qing ;
Bandosz, Teresa J. .
ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (03) :438-447