Perfluorocarbon-soluble catalysts and reagents and the application of FBS (fluorous biphase system) to organic synthesis

被引：118

作者：

Cavazzini, M

Montanari, F

Pozzi, G

Quici, S

机构：

[1] CNR, Ctr Sintesi & Stereochim Speciali Sistemi Organ, I-20133 Milan, Italy

[2] Univ Milan, Dipartimento Chim Organ & Ind, I-20133 Milan, Italy

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1999年 / 94卷 / 02期

关键词：

fluorous biphase systems;

D O I：

10.1016/S0022-1139(98)00358-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new phase-separation and immobilization technique known as FBS (fluorous biphase system) is becoming more and more popular among researchers in both industry and academia. The immiscibility of perfluorocarbons with most organic solvents and water is of great advantage, in that it allows the easy recovery and recycling of the catalysts and reagents. The major results so far obtained in this field are discussed. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：183 / 193

页数：11

共 56 条

[1] [Anonymous], [No title captured], Patent No. 5463082
[2] Banks R. E., 1979, ORGANOFLUORINE CHEM
[3] Banks R.E, 1982, PREPARATION PROPERTI
[4] Banks R.E., 1994, ORGANOFLUORINE CHEM
[5] A soluble fluorous phase polymer support
Bergbreiter, DE
Franchina, JG
[J]. CHEMICAL COMMUNICATIONS, 1997, (16) : 1531 - 1532
[6] Palladium-catalyzed cross-coupling of organozinc bromides with aryl iodides in perfluorinated solvents
Betzemeier, B
Knochel, P
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (23) : 2623 - 2624
[7] Wacker oxidation of alkenes using a fluorous biphasic system. A mild preparation of polyfunctional ketones
Betzemeier, B
Lhermitte, F
Knochel, P
[J]. TETRAHEDRON LETTERS, 1998, 39 (37) : 6667 - 6670
[8] Perfluorocarbons as novel reaction media for photooxidation reactions
Chambers, RD
Sandford, G
Shah, A
[J]. SYNTHETIC COMMUNICATIONS, 1996, 26 (10) : 1861 - 1866
[9] EXCITING RESULTS FROM THE FIELD OF HOMOGENEOUS 2-PHASE CATALYSIS
CORNILS, B
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (15): : 1575 - 1577
[10] CORNILS B, 1997, ANGEW CHEM INT EDIT, V36, P2059

← 1 2 3 4 5 6 →