Wacker oxidation of alkenes using a fluorous biphasic system. A mild preparation of polyfunctional ketones

被引:61
作者
Betzemeier, B [1 ]
Lhermitte, F [1 ]
Knochel, P [1 ]
机构
[1] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany
关键词
D O I
10.1016/S0040-4039(98)01355-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Various alkenes are oxidized to the corresponding ketones using t-BuOOH in the presence of a palladium(II) catalyst bearing perfluorinated ligands using a biphasic solvent system of benzene and bromoperfluorooctane. (C) 1998 Elsevier Science Ltd. All rights reserved.
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页码:6667 / 6670
页数:4
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