Single enantiomer, chiral donor-acceptor metal complexes from bisoxazoline pseudoracemates

被引：30

作者：

Atkins, Jeffery M. ^{[1
]}

Moteki, Shin A.

DiMagno, Stephen G.

Takacs, James M.

机构：

[1] Univ Nebraska, Dept Chem, Lincoln, NE 68588 USA

[2] Univ Nebraska, Ctr Mat Res & Anal, Lincoln, NE 68588 USA

来源：

ORGANIC LETTERS | 2006年 / 8卷 / 13期

关键词：

D O I：

10.1021/ol060836s

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Single enantiomer, chiral donor-acceptor metal complexes were synthesized via the self-discriminating zinc(II) complexation of a pseudoracemic mixture of donor/acceptor-substituted bisoxazoline derivatives.

引用

页码：2759 / 2762

页数：4

共 35 条

[21] ORGANOMETALLIC COMPOUNDS FOR NONLINEAR OPTICS - THE SEARCH FOR EN-LIGHT-ENMENT [J].

LONG, NJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (01) :21-38

[22] Amidines derived from Pt(IV)-mediated nitrile-amino alcohol coupling and their Zn(II)-catalyzed conversion into oxazolines [J].

Makarycheva-Mikhailova, AV ;

Kukushkin, VY ;

Nazarov, AA ;

Garnovskii, DA ;

Pombeiro, AJL ;

Haukka, M ;

Keppler, BK ;

Galanski, M .

INORGANIC CHEMISTRY, 2003, 42 (08) :2805-2813

[23]

SAALFRANK RW, 1994, Z NATURFORSCH B, V49, P1415

[24]

Schulze V, 1999, CHEM-EUR J, V5, P337, DOI 10.1002/(SICI)1521-3765(19990104)5:1<337::AID-CHEM337>3.0.CO

[25]

2-P

[26] Enantioselective conjugate addition of silylketene acetals to β-enamidomalonates.: Synthesis of β-amino acid derivatives [J].

Sibi, MP ;

Chen, JX .

ORGANIC LETTERS, 2002, 4 (17) :2933-2936

[27] THE REACTION OF POLYSUBSTITUTED AROMATICS .62. ANOMALOUS REACTION OF ARYLMALONONITRILES WITH NITRIC-ACID - PARA-DIRECTING NATURE OF DICYANOMETHYL GROUP AND A THROUGH-RING NITRO/ACI-NITRO TAUTOMERISM OF 4-NITROPHENYLMALONONITRILE [J].

SUZUKI, H ;

KOIDE, H ;

OGAWA, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1988, 61 (02) :501-504

[28] Rhodium-catalyzed asymmetric hydrogenation using self-assembled chiral bidentate ligands [J].

Takacs, JM ;

Chaiseeda, K ;

Moteki, SA ;

Reddy, DS ;

Wu, D ;

Chandra, K .

PURE AND APPLIED CHEMISTRY, 2006, 78 (02) :501-509

[29] The selective formation of neutral, heteroleptic zinc(II) complexes via self-discrimination of chiral bisoxazoline racemates and pseudoracemates [J].

Takacs, JM ;

Hrvatin, PM ;

Atkins, JM ;

Reddy, DS ;

Clark, JL .

NEW JOURNAL OF CHEMISTRY, 2005, 29 (02) :263-265

[30] Asymmetric catalysis using self-assembled chiral bidentate P,P-ligands [J].

Takacs, JM ;

Reddy, DS ;

Moteki, SA ;

Wu, D ;

Palencia, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (14) :4494-4495

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