Exploratory studies probing the intermediacy of azomethine ylides in the photochemistry of N-phthaloyl derivatives of α-amino acids and β-amino alcohols.

被引：14

作者：

Yoon, UC ^{[1
]}

Lee, CW

Oh, SW

Mariano, PS

机构：

[1] Pusan Natl Univ, Coll Nat Sci, Dept Chem, Pusan 699735, South Korea

[2] Univ New Mexico, Dept Chem, Albuquerque, NM 87131 USA

来源：

TETRAHEDRON | 1999年 / 55卷 / 41期

基金：

美国国家科学基金会;

关键词：

photochemistry; mechanisms; imides; amino acid derivatives;

D O I：

10.1016/S0040-4020(99)00702-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Exploratory photochemical studies with N-phthaloyl derivatives of glutamic acid, aspartic acid, serine, threonine and analogous carboxylic acids and alcohols have been conducted to determine the generality of azomethine ylide forming decarboxylation and retro-aldol fragmentation reactions. Preferences in the competition between these excited state reaction pathways have been determined by studies with phthalimides which contain both alpha-amino acid and beta-aminoethanol groups. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：11997 / 12008

页数：12

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