Growing Crystalline Zinc-1,3,5-benzenetricarboxylate Metal-Organic Frameworks in Different Surfactants

被引：163

作者：

Gao, Junkuo ^{[1
,2
]}

Ye, Kaiqi ^{[3
]}

Yang, Ling ^{[1
]}

Xiong, Wei-Wei ^{[1
]}

Ye, Ling ^{[3
]}

Wang, Yue ^{[3
]}

Zhang, Qichun ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore

[2] Zhejiang Sci Tech Univ, Coll Mat & Text, Hangzhou 310018, Zhejiang, Peoples R China

[3] Jilin Univ, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China

来源：

INORGANIC CHEMISTRY | 2014年 / 53卷 / 02期

关键词：

PROMOTED DISSOLUTION; THERMAL METHOD; IONIC LIQUIDS; CLUSTER; MICROPARTICLES; POSTCHEMISTRY; COORDINATION; PARTICLES;

D O I：

10.1021/ic402692p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Six new zinc-1,3,5-benzenetricarboxylate-based metal organic frameworks (MOFs) have been successfully synthesized using three different surfactants (PEG 400, octanoic acid, and hexadecyltributylphosphonium bromide) as reaction media. These surfactants with different characteristics, such as being neutral, acidic, and cationic, have been demonstrated to show strong effects on directing the crystals' growth and resulted in different secondary building units (SBUs) including an unusual SBU unit [Zn-4(mu(4)-O)(CO2)(7)]. Our results clearly indicated that the surfactant thermal method could offer exciting opportunities for preparing novel MOFs or other inorganic crystalline materials with diverse structures and interesting properties.

引用

页码：691 / 693

页数：3

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