Triptycene based luminescent metal-organic gels for chemosensing

被引：96

作者：

Barman, Samir ^{[1
]}

Garg, Jai Anand ^{[1
]}

Blacque, Olivier ^{[1
]}

Venkatesan, Koushik ^{[1
]}

Berke, Heinz ^{[1
]}

机构：

[1] Univ Zurich, Dept Inorgan Chem, CH-8057 Zurich, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 90期

基金：

瑞士国家科学基金会;

关键词：

EXPLOSIVES DETECTION; CHEMICAL SENSORS; POLYMER SENSORS; FLUORESCENT; COORDINATION; IPTYCENES; DESIGN; TNT; FILMS;

D O I：

10.1039/c2cc34430k

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

We report a novel luminescent Al-based metal-organic gel G1 comprising 1,4,5,8-triptycenetetracarboxylic acid, which exhibits highly sensitive detection towards nitro aromatic compounds particularly picric acid. Furthermore, under identical reaction conditions, using a Co(II) salt instead, a novel 3D framework material, trip-MOF-1, was isolated and its sensitivity towards picric acid was also evaluated.

引用

收藏

页码：11127 / 11129

页数：3

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