Formation of 1:1 complexes of ferrocene-containing salen ligands with Mg, Ti and Zr

被引：62

作者：

Shafir, A

Fiedler, D

Arnold, J ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Chem Sci, Berkeley, CA 94720 USA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 04期

关键词：

D O I：

10.1039/b107066p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Condensation of 1,1'-diaminoferrocene with a range of salicylaldehydes resulted in the formation of the corresponding salen-type ligands in high yields. The ability of these compounds to serve as ligands was demonstrated by the formation of several 1 : 1 Zr and Ti complexes, one of which was structurally characterized and was found to feature a (t-Bu)Salfen(2-) ligand in a square-planar conformation. In addition, a related Schiff-base ligand was synthesized by condensing diaminoferrocene with 2,4-petanedione and a Zr complex of this ligand was isolated.

引用

页码：555 / 560

页数：6

共 22 条

[1] Synthesis and metallation of ferrocenylimines derived from ligating diaminoheteroarenes [J].