A ferrocene functionalised macrocyclic receptor for cations and anions

被引：55

作者：

Beer, PD

Bernhardt, PV ^{[1
]}

机构：

[1] Univ Queensland, Dept Chem, Brisbane, Qld 4072, Australia

[2] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 09期

关键词：

D O I：

10.1039/b100439p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The isolation and characterisation of a new macrocyclic hexaamine trans-6,13-bis(ferrocenylmethylamino)-6,13-dimethyl-1,4,8,11-tetraazacyclotetradecane (L-2) bearing two ferrocenyl groups appended to its exocyclic amines is reported. The crystal structures of L-2 and its dihydrochloride salt L-2. 2HCl . 2H(2)O have been determined. In the latter case cation-anion hydrogen bonding is observed in the solid state. Substrate binding by the electroactive L-2 in MeCN-CH2Cl2 solution has been examined by cyclic voltammetry and reveals the receptor electrochemically to recognise benzoate and chloride anions. The macrocyclic N-donors may also bind transition metal cations such as Cu-II and Zn-II.

引用

收藏

页码：1428 / 1431

页数：4

相关论文

共 25 条

[1]

[Anonymous], 1998, PROGRAMS CRYSTAL STR

[2] Transition-metal receptor systems for the selective recognition and sensing of anionic guest species [J].

Beer, PD .

ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (02) :71-80

[3] Electrochemical and optical sensing of anions by transition metal based receptors [J].

Beer, PD ;

Cadman, J .

COORDINATION CHEMISTRY REVIEWS, 2000, 205 :131-155

[4] Electrochemical molecular recognition: pathways between complexation and signalling [J].

Beer, PD ;

Gale, PA ;

Chen, GZ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (12) :1897-1909

[5] COORDINATION OF 6,13-DIMETHYL-1,4,8,11-TETRA-AZACYCLOTETRADECANE-6,13-DIAMINE TO PLATINUM(II) AND PALLADIUM(II) - SYNTHESES, CHARACTERIZATION, AND X-RAY CRYSTAL-STRUCTURES OF THE PERCHLORATE SALTS OF BOTH COMPLEXES [J].

BERNHARDT, PV ;

LAWRANCE, GA ;

PATALINGHUG, WC ;

SKELTON, BW ;

WHITE, AH ;

CURTIS, NF ;

SIRIWARDENA, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (09) :2853-2858

[6] ISOLATION AND COMPLEXATION OF THE CIS ISOMER OF THE PENDANT ARM MACROCYCLE 6,13-DIMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE-6,13-DIAMINE [J].

BERNHARDT, PV ;

COMBA, P ;

HAMBLEY, TW ;

LAWRANCE, GA ;

VARNAGY, K .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (03) :355-359

[7] Structurally reinforced tetraazamacrocyclic complexes [J].

Bernhardt, PV ;

Sharpe, PC .

INORGANIC CHEMISTRY, 2000, 39 (10) :2020-2025

[8] CRYSTAL-STRUCTURES OF [H4L] (CLO4)4.6H2O AND [ZN(H2L)(S2O6)2].4H2O (L = 6,13-DIMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE-6,13-DIAMINE) [J].

BERNHARDT, PV ;

HAMBLEY, TW ;

LAWRANCE, GA .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1990, 43 (04) :699-706

[9] New stereoselective routes to macrocyclic ligands [J].

Bernhardt, PV ;

Sharpe, PC .

INORGANIC CHEMISTRY, 1998, 37 (07) :1629-1636

[10] SEXIDENTATE COORDINATION OF THE PENDANT-ARM MACROCYCLE 6,13-DIMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE-6,13-DIAMINE (L1) TO ZINC(II) - CRYSTAL-STRUCTURE OF [ZNL1][CLO4]2.H2O [J].

BERNHARDT, PV ;

LAWRANCE, GA ;

MAEDER, M ;

ROSSIGNOLI, M ;

HAMBLEY, TW .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (05) :1167-1182