A highly enantioselective organocatalyst for the Michael addition of cyclic ketones to nitroolefins

被引：75

作者：

Zhu, MK

Cun, LF

Mi, AQ

Jiang, YZ

Gong, LZ ^{[1
]}

机构：

[1] Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing, Peoples R China

来源：

TETRAHEDRON-ASYMMETRY | 2006年 / 17卷 / 04期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1016/j.tetasy.2006.01.034

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Enantiomerically pure triamine 2, which catalyses the Michael addition of cyclic ketones to nitroolefins with high diastereoselectivity (LIP to 99:1) and enantioselectivity (LIP to 91% ee), was designed and prepared. (c) 2006 Published by Elsevier Ltd.

引用

页码：491 / 493

页数：3

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