A μ-η2:η2-disulfide dicopper(II) complex from reaction of S8 with a copper(I) precursor:: Reactivity of the bound disulfur moiety

被引：32

作者：

Helton, ME

Maiti, D

Zakharov, LN

Rheingold, AL

Porco, JA

Karlin, KD

机构：

[1] Johns Hopkins Univ, Dept Chem, Baltimore, MD 21218 USA

[2] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA

[3] Boston Univ, Ctr Chem Methodol & Lib Dev, Boston, MA 02215 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 07期

关键词：

atom transfer; bioinorganic chemistry; copper; N ligands; sulfur;

D O I：

10.1002/anie.200503216

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Side on: Elemental sulfur (S8) reacts with a tridentate chelate (MePY2)Me2N copper(I) compound, generating a side on μ-η2:η2-disulfido bridged complex [{CuII-(MePY2)Me2N}2(S2 2-)]2+ (see structure: yellow S, green Cu, blue N, gray C); its reactivity towards PPh3, RNC, CO, O2, PhCH 2Br, and a tetradentate chelating ligand are described. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：1138 / 1141

页数：4

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