Investigation by 1H-29 SiHETCOR NMR experiments of surfactant/silica interfaces in mesostructured materials with ordered porosity

被引:11
作者
Baccile, N [1 ]
Maquet, J [1 ]
Babonneau, F [1 ]
机构
[1] Univ Paris 06, UMR 7574, F-75252 Paris 05, France
关键词
SBA-3; mesoporous silica; MCM-41; 2D NMR spectroscopy;
D O I
10.1016/j.crci.2005.06.021
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Just after the discovery, in the early 1990s, of surfactant-templated mesostructured materials, models to describe the surfactant/silica interface have been proposed, based on few experimental evidences. Two-dimensional heteronuclear correlation (HETCOR) experiments based on H-1-Si-29 dipolar coupling appear as a very powerful tool to investigate the hybrid organic-inorganic interfaces.
引用
收藏
页码:478 / 484
页数:7
相关论文
共 34 条
[1]   Micellar solubilization:: Structural and conformational changes investigated by 1H and 13C liquid-state NMR [J].
Alonso, B ;
Harris, RK ;
Kenwright, AM .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2002, 251 (02) :366-375
[2]   X-RAY-DIFFRACTION STUDY OF MESOPHASES OF CETYLTRIMETHYLAMMONIUM BROMIDE IN WATER, FORMAMIDE, AND GLYCEROL [J].
AUVRAY, X ;
PETIPAS, C ;
ANTHORE, R ;
RICO, I ;
LATTES, A .
JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (21) :7458-7464
[3]   A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].
BECK, JS ;
VARTULI, JC ;
ROTH, WJ ;
LEONOWICZ, ME ;
KRESGE, CT ;
SCHMITT, KD ;
CHU, CTW ;
OLSON, DH ;
SHEPPARD, EW ;
MCCULLEN, SB ;
HIGGINS, JB ;
SCHLENKER, JL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843
[4]  
Brinker C.J., 1989, SOL GEL SCI PHYS CHE
[5]  
Brinker CJ, 1999, ADV MATER, V11, P579, DOI 10.1002/(SICI)1521-4095(199905)11:7<579::AID-ADMA579>3.3.CO
[6]  
2-I
[7]   Molecularly ordered inorganic frameworks in layered silicate surfactant mesophases [J].
Christiansen, SC ;
Zhao, DY ;
Janicke, MT ;
Landry, CC ;
Stucky, GD ;
Chmelka, BF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (19) :4519-4529
[8]   Ordered mesoporous materials [J].
Ciesla, U ;
Schüth, F .
MICROPOROUS AND MESOPOROUS MATERIALS, 1999, 27 (2-3) :131-149
[9]   From microporous to mesoporous molecular sieve materials and their use in catalysis [J].
Corma, A .
CHEMICAL REVIEWS, 1997, 97 (06) :2373-2419
[10]   Synthesis and characterization of V-SBA-1 cubic mesoporous molecular sieves [J].
Dai, LX ;
Tabata, K ;
Suzuki, E ;
Tatsumi, T .
CHEMISTRY OF MATERIALS, 2001, 13 (01) :208-212