Bis(2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-pentaoxabenzo[b]cyclopentadecene-O-1,O-4,O-7,O-10,O-13)sodium(1+) 1,1,7,7-tetracyano-3,5-dithiahepta-1,6-diene-2,6-dithiolate(2-) (2/1)

被引：9

作者：

Long, DL ^{[1
]}

Jin, QH ^{[1
]}

Xin, XQ ^{[1
]}

Yu, KB ^{[1
]}

机构：

[1] ACAD SINICA,CHENGDU CTR ANAL & DETERMINAT,CHENGDU 610041,PEOPLES R CHINA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1997年 / 53卷

关键词：

D O I：

10.1107/S010827019601517X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cation of the title compound, 2[Na(C14H20O5)(2)](+).- C9H2N4S42-, comprises two configurations of benzo-15-crown-5-sodium complex cations in which the Na atoms are sandwiched by ligands through coordinated O atoms. The Na-O distances are in the range 2.443 (4)- 3.003 (3) Angstrom. The anion portion is a partially alkylated product of isomalononitriledithiolate (C4N2S22-). The sulfide S-C distances are in the range 1.769 (4) - 1.796 (4) A, while those of the thiol moieties are in the range 1.667 (4) - 1.671 (4) Angstrom.

引用

页码：554 / 556

页数：3

共 13 条

[1] CRYSTAL-STRUCTURES OF COMPLEXES BETWEEN ALKALI-METAL SALTS AND CYCLIC POLYETHERS .3. AQUO-(2,3-BENZO-1,4,7,10,13-PENTAOXACYCLOPENTADEC-2-ENE)SODIUM IODIDE [J].

BUSH, MA ;

TRUTER, MR .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1972, (03) :341-&

[2] MACROCYCLIC POLYFUNCTIONAL LEWIS-BASES .11. STRUCTURE OF TRICHLOROCUPRATES OF CROWN-COMPLEXED SODIUM [J].

DREISSIG, W ;

DAUTER, Z ;

CYGAN, A ;

BIERNAT, JF .

INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 96 (01) :21-27

[3] CHEMISTRY OF SUBVALENT MAIN GROUP-METALS WITH DITHIOLATES .2. X-RAY STRUCTURAL, THERMAL, AND THEORETICAL INVESTIGATIONS ON THE NOVEL ONE-DIMENSIONAL STACKING STRUCTURE K2[PB(S2C=C(CN)2)2].2H2O [J].

HUMMEL, HU ;

MESKE, H .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (04) :627-630

[4] STRUCTURE OF SODIUM 1,1-DICYANOETHYLENE-2,2-DITHIOLATE TRIHYDRATE [J].

HUMMEL, HU .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1987, 43 :41-43

[5] A NOVEL SQUARE-PLANAR CD(II) WITH 4 SULFUR DONOR LIGANDS - CRYSTAL-STRUCTURE AND CD-113 NMR [J].

LI, HY ;

AMMA, EL .

INORGANICA CHIMICA ACTA, 1990, 177 (01) :5-7

[6] Syntheses and crystal structures of isomalononitrile dithiolato complexes (Bu(4)N)(2)Zn(i-mnt)(2) and (Et(4)N)(2)Pd(i-mnt)(2) [J].

Long, DL ;

Hou, HW ;

Xin, XQ ;

Yu, KB ;

Luo, BS ;

Chen, LR .

JOURNAL OF COORDINATION CHEMISTRY, 1996, 38 (1-2) :15-24

[7]

MOODY DC, 1979, CRYST STRUCT COMMUN, V8, P933

[8] CRYSTAL-STRUCTURES OF COMPLEXES BETWEEN ALKALI-METAL SALTS AND CYCLIC POLYETHERS .11. COMPLEXES FORMED BETWEEN 2,3,5,6,8,9,11,12-OCTAHYDRO-1,4,7,10,13-BENZOPENTAOXACYCLOPENTADECIN (BENZO-15-CROWN-5) AND SODIUM-PERCHLORATE (1-1), SODIUM-PERCHLORATE (2-1), AND SODIUM TETRAPHENYLBORATE (2-1) [J].

OWEN, JD .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (07) :1066-1075

[9]

SHELDRICK GM, 1993, SHELXL93 PROGRAM REF

[10]

SHELDRICK GM, 1990, SHELXTL USER MANUAL

← 1 2 →