Catalytic asymmetric synthesis of optically active alkenes by palladium-catalysed asymmetric reduction of racemic allylic esters with formic acid

被引:23
作者
Hayashi, T
Kawatsura, M
Iwamura, H
Yamaura, Y
Uozumi, Y
机构
[1] Department of Chemistry, Faculty of Science, Kyoto University, Sakyo
关键词
D O I
10.1039/cc9960001767
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Asymmetric reduction of racemic allyl esters, e.g. methyl 1-vinyl-1,2,3,4-tetrahydronaphth-1-yl carbonate, which contain two different alkyl groups at the alpha-position, with formic acid in the presence of 1 mol% of palladium catalyst coordinated with (R)-3-diphenylphosphino-3'methoxy-4,4'-biphenanthryl [(R)-MOP-phen] ligand gives optically active terminal alkenes in up to 93% ee.
引用
收藏
页码:1767 / 1768
页数:2
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