Homogeneous oxidation of aromatics in nucleus with peracetic acid catalyzed by iron and manganese phthalocyanine complexes

被引：43

作者：

Barkanova, SV

Derkacheva, VM

Dolotova, OV

Li, VD

Negrimovsky, VM

Kaliya, OL

Lukyanets, EA

机构：

[1] Organ. Intermediates and Dyes Inst., 103787 Moscow

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 10期

关键词：

D O I：

10.1016/0040-4039(96)00079-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of naphthalene and methylnaphthalenes with peracetic acid catalyzed by Mn(III) (1) or Fe(II) (2) octanitrophthalocyanines in CH3CN at 20 degrees C produces 1,4-naphthoquinones with 35-62% yields. The corresponding 2,3-epoxide-1,4-endoperoxides are proposed as intermediate in reaction catalyzed by 1.

引用

页码：1637 / 1640

页数：4

共 19 条

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