PORPHYRINS AND AZAPORPHINES AS CATALYSTS IN ALKENE EPOXIDATIONS WITH PERACETIC-ACID

被引：39

作者：

BANFI, S

MONTANARI, F

QUICI, S

BARKANOVA, SV

KALIYA, OL

KOPRANENKOV, VN

LUKYANETS, EA

机构：

[1] CNR,CTR STUDIO SINTESI & STEREOCHIM SPECIALI SISTEMI,I-20135 MILAN,ITALY

[2] MOSCOW ORGAN INTERMED & DYE RES INST,MOSCOW 103787,RUSSIA

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 13期

关键词：

D O I：

10.1016/0040-4039(95)00244-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

the reactivities of five Mn-III(Cl) - porphinoids were compared in the catalytic alkene epoxidations in CH3CN solution with peracetic acid as primary oxidant Porphyrins 1 and 2 bearing Cl and NO2 substituents showed the best efficiency while tetraazaporphyrin 5 was found to bean interesting catalyst for terminal alkene epoxidations.

引用

收藏

页码：2317 / 2320

页数：4

相关论文

共 17 条

[1] MECHANISM OF MANGANESE PORPHYRIN-CATALYZED OXIDATION OF ALKENES - ROLE OF MANGANESE(IV) OXO SPECIES [J].

ARASASINGHAM, RD ;

HE, GX ;

BRUICE, TC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (18) :7985-7991

[2] HYDROGEN-PEROXIDE OXYGENATION OF ALKANES CATALYZED BY MANGANESE(III)-TETRAARYLPORPHYRINS - THE REMARKABLE CO-CATALYTIC EFFECT OF LIPOPHILIC CARBOXYLIC-ACIDS AND HETEROCYCLIC BASES [J].

BANFI, S ;

MAIOCCHI, A ;

MOGGI, A ;

MONTANARI, F ;

QUICI, S .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (24) :1794-1796

[3] INVESTIGATION ON FACTORS RULING CATALYTIC EFFICIENCY AND CHEMICAL-STABILITY OF MN(III) PORPHYRINS IN HOCL OLEFIN EPOXIDATION - CONDITIONS FOR PRACTICAL APPLICATION [J].

BANFI, S ;

MONTANARI, F ;

QUICI, S .

JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (08) :1850-1859

[4]

BARKANOVA SV, 1991, STUD SURF SCI CATAL, V66, P471

[5]

DERKACHEVA VM, 1991, STUD SURF SCI CATAL, V61, P461

[6] IRON OCTAETHYLTETRAAZAPORPHYRINS - SYNTHESIS, CHARACTERIZATION, COORDINATION CHEMISTRY, AND COMPARISONS TO RELATED IRON PORPHYRINS AND PHTHALOCYANINES [J].

FITZGERALD, JP ;

HAGGERTY, BS ;

RHEINGOLD, AL ;

MAY, L ;

BREWER, GA .

INORGANIC CHEMISTRY, 1992, 31 (11) :2006-2013

[7] METAL-CENTERED OXYGEN ATOM TRANSFER-REACTIONS [J].

HOLM, RH .

CHEMICAL REVIEWS, 1987, 87 (06) :1401-1449

[8]

JORGENSEN KA, 1987, J AM CHEM SOC, V109, P698

[9]

KOBAYASHI S, 1991, CHEM PHARM BULL, V39, P3025

[10] FACTORS CONTROLLING THE REACTIVITY OF A LIGNINASE MODEL BASED ON THE ASSOCIATION OF POTASSIUM MONOPERSULFATE TO MANGANESE AND IRON PORPHYRIN COMPLEXES [J].

LABAT, G ;

MEUNIER, B .

JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (21) :5008-5011