Self-assembly of triptycene-based cylindrical macrotricyclic host with dibenzylammonium ions: Construction of dendritic [3]pseudorotaxanes

被引:59
作者
Zong, QS
Zhang, C
Chen, CF [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Ctr Mol Sci, Beijing 100049, Peoples R China
关键词
D O I
10.1021/ol0604419
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
It was found that a cylindrical macrotricyclic host containing two dibenzo[24]crown-8 cavities could self-assemble with two dibenzylammonium salts to form a stable 1:2 complex in solution and in the solid state, in which multiple hydrogen-bonding and pi-pi stacking interactions between the host and the guest played an important role. Furthermore, a series of dendritic pseudorotaxanes were constructed and structurally studied.
引用
收藏
页码:1859 / 1862
页数:4
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