Self-assembly of dendrimers by slippage

被引：60

作者：

Elizarov, AM ^{[1
]}

Chang, T ^{[1
]}

Chiu, SH ^{[1
]}

Stoddart, JF ^{[1
]}

机构：

[1] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

来源：

ORGANIC LETTERS | 2002年 / 4卷 / 21期

关键词：

D O I：

10.1021/ol026479c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] A dendrimer with rotaxane-like characteristics has been assembled under thermodynamic control from complementary wedge-shaped precursors by slippage in CH2Cl2. The driving force for the self-assembly process is the molecular recognition that exists as a result of [N+-H...O] and [C-H...O] hydrogen bonds between an NH2+ center in one Frechet-type benzyl ether wedge and a dibenzo[24]crown-8 unit that links the other two such wedges.

引用

页码：3565 / 3568

页数：4

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