Direct synthesis of deep cavity p-phenylcalix[4]arene in poly(ethylene glycol), and its self-association in the solid state

被引：12

作者：

Makha, M ^{[1
]}

Raston, CL ^{[1
]}

Sobolev, AN ^{[1
]}

机构：

[1] Univ Western Australia, Sch Biomed Biomol & Chem Sci, Perth, WA 6009, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2006年 / 59卷 / 04期

关键词：

D O I：

10.1071/CH06080

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

p- Phenylcalix[4] arene is formed directly from p- phenylphenol in 66% yield (50% isolated yield) using poly( ethylene glycol) as the reaction medium, with crystallization of the pure cavitand from toluene mediated by p- carborane. The solid-state structure comprises interlocking columnar arrays.

引用

页码：260 / 262

页数：3

共 18 条

[1] A new type of material for the recovery of hydrogen from gas mixtures [J].

Atwood, JL ;

Barbour, LJ ;

Jerga, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (22) :2948-2950

[2] Controlling van der Waals contacts in complexes of fullerene C60 [J].

Atwood, JL ;

Barbour, LJ ;

Heaven, MW ;

Raston, CL .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (28) :3254-3257

[3] Polymorphism of pure p-tert-butylcalix[4]arene:: conclusive identification of the phase obtained by desolvation [J].

Atwood, JL ;

Barbour, LJ ;

Jerga, A .

CHEMICAL COMMUNICATIONS, 2002, (24) :2952-2953

[4] Storage of methane and freon by interstitial van der Waals confinement [J].

Atwood, JL ;

Barbour, LJ ;

Jerga, A .

SCIENCE, 2002, 296 (5577) :2367-2369

[5] Polyethylene glycol and solutions of polyethylene glycol as green reaction media [J].

Chen, J ;

Spear, SK ;

Huddleston, JG ;

Rogers, RD .

GREEN CHEMISTRY, 2005, 7 (02) :64-82

[6] Bioharmaceutical applications of calixarenes [J].

Da Silva, E ;

Lazar, AN ;

Coleman, AW .

JOURNAL OF DRUG DELIVERY SCIENCE AND TECHNOLOGY, 2004, 14 (01) :3-20

[7] CALIXARENES .16. FUNCTIONALIZED CALIXARENES - THE DIRECT SUBSTITUTION ROUTE [J].

GUTSCHE, CD ;

PAGORIA, PF .

JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (26) :5795-5802

[8] THIOCALIX[4]ARENES .1. SYNTHESIS AND STRUCTURE OF ETHYLTHIOCALIX[4]ARENE METHYL-ETHER AND THE RELATED STRUCTURE OF BROMOCALIX[4]ARENE METHYL-ETHER [J].

HAMADA, F ;

BOTT, SG ;

ORR, GW ;

COLEMAN, AW ;

ZHANG, HM ;

ATWOOD, JL .

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, 1990, 9 (03) :195-206

[9] SYNTHESIS AND CHARACTERIZATION OF RIGID, DEEP-CAVITY CALIX[4]ARENES [J].

JUNEJA, RK ;

ROBINSON, KD ;

JOHNSON, CP ;

ATWOOD, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (09) :3818-3819

[10] Inter-digitation approach to encapsulation of C60:: [C60 ⊂ (p-phenylcalix[5]arene)2] [J].

Makha, M ;

Hardie, MJ ;

Raston, CL .

CHEMICAL COMMUNICATIONS, 2002, (14) :1446-1447

← 1 2 →