Electron-impact ionization cross sections for elements Z=1 to Z=54

被引:77
作者
Bartlett, PL [1 ]
Stelbovics, AT [1 ]
机构
[1] Murdoch Univ, Ctr Atom Mol & Surface Phys, Murdoch, WA 6150, Australia
基金
澳大利亚研究理事会;
关键词
D O I
10.1016/j.adt.2003.11.006
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
The electron-impact ionization cross sections for all neutral ground-state elements H-Xe (Z = 1 to Z = 54) have been calculated using the plane wave Born approximation. The atomic orbital wavefunctions have been approximated by Roothaan-Hartree-Fock Slater functions, and the scattered and ejected electrons have been approximated by a plane wave and Coulomb wave, respectively. Full orthogonalization of the Coulomb wave with the occupied atomic orbitals has been performed, which improves the correspondence with experimental data at low- and mid-energies. Results are presented for the total ionization cross section and the partial ionization cross sections of the largest contributing orbitals for each atom. (C) 2003 Elsevier Inc. All rights reserved.
引用
收藏
页码:235 / 265
页数:31
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