Structural and mechanistic studies of Pd-catalyzed C-C bond formation:: The case of carbonylation and Heck reaction

被引：185

作者：

Trzeciak, AM ^{[1
]}

Ziólkowski, JJ ^{[1
]}

机构：

[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

来源：

COORDINATION CHEMISTRY REVIEWS | 2005年 / 249卷 / 21-22期

关键词：

palladium complexes; Palladium(0) colloid; C-C coupling; heck reaction; carbonylation reaction;

D O I：

10.1016/j.ccr.2005.02.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The extraordinary catalytic activity of palladium in C-C bond forming processes is reviewed in respect to Heck and carbonylation reactions. Examples of catalytic systems based on palladium complexes with phosphorus ligands and phosphine-free systems and based on the Pd(0) colloid are presented. The two key steps of both reaction mechanisms: first, reduction of Pd(II) to Pd(0) complexes or Pd(0) colloids and second, oxidative addition of substrates (aryl or benzyl halides) are discussed. (c) 2005 Elsevier B.V. All rights reserved.

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页码：2308 / 2322

页数：15

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