Palladium catalyzed hydroxycarbonylation of olefins in biphasic system: beneficial effect of alkali metal salt and protective-colloid agents on the stability of the catalytic system

被引：33

作者：

Bertoux, F

Monflier, E

Castanet, Y

Mortreux, A

机构：

[1] Univ Sci & Tech Lille Flandres Artois, Fac Sci J Perrin, Lab Physicochim Interfaces & Applicat, F-62307 Lens, France

[2] CNRS, Catalyse Heterogene & Homogene Lab, F-59659 Villeneuve Dascq, France

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1999年 / 143卷 / 1-3期

关键词：

hydroxycarbonylation; olefin; two-phase system; palladium; alkali metal halides; colloids;

D O I：

10.1016/S1381-1169(98)00359-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The addition of an alkali metal halide or a protective-colloid agent like polyvinylalcohol to water-soluble hydroxycarbonylation catalyst derived from PdCl2 and the sulfonated phosphine TPPTS prevents the catalyst decay and allows to maintain high activities. The role of these additives is discussed, in relation with the reaction mechanism. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：23 / 30

页数：8

共 28 条

[1] THE REGIOSPECIFIC PALLADIUM CATALYZED HYDROCARBOXYLATION OF ALKENES UNDER MILD CONDITIONS [J].

ALPER, H ;

WOELL, JB ;

DESPEYROUX, B ;

SMITH, DJH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (21) :1270-1271

[2]

ALPER H, 1994, Patent No. 01376

[3] PROGRESS IN HYDROFORMYLATION AND CARBONYLATION [J].

BELLER, M ;

CORNILS, B ;

FROHNING, CD ;

KOHLPAINTNER, CW .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 104 (01) :17-85

[4]

BERTOUX F, 1998, IN PRESS J MOL CATAL

[5] CATALYTIC CARBONYLATION OF ETHYLENE IN THE PRESENCE OF THE PD(ACAC)(2)-M-PH(2)PC6H4SO3NA(H)-ACOH SYSTEM [J].

CHEPAIKIN, EG ;

BEZRUCHENKO, AP ;

LESHCHEVA, AA ;

BOIKO, GN .

RUSSIAN CHEMICAL BULLETIN, 1994, 43 (03) :360-363

[6]

CORNILS B, 1996, APPL HOMOGENEOUS CAT, P104

[7] REACTION ACTIVITY AND SELECTIVITY AS A FUNCTION OF SOLUTION IONIC-STRENGTH IN OCT-1-ENE HYDROFORMYLATION WITH SULFONATED PHOSPHINES [J].

DING, H ;

HANSON, BE .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (24) :2747-2748

[8] THE EFFECT OF SALT ON SELECTIVITY IN WATER-SOLUBLE HYDROFORMYLATION CATALYSTS [J].

DING, H ;

HANSON, BE ;

GLASS, TE .

INORGANICA CHIMICA ACTA, 1995, 229 (1-2) :329-333

[9] SPECTATOR CATIONS AND CATALYSIS WITH SULFONATED PHOSPHINES - THE ROLE OF CATIONS IN DETERMINING REACTION SELECTIVITY IN THE AQUEOUS-PHASE HYDROFORMYLATION OF OLEFINS [J].

DING, H ;

HANSON, BE .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 99 (03) :131-137

[10] NOBLE-METAL CATALYSIS .2. HYDRATOCARBONYLATION REACTION OF OLEFINS WITH CARBON-MONOXIDE TO GIVE SATURATED ACIDS [J].

FENTON, DM .

JOURNAL OF ORGANIC CHEMISTRY, 1973, 38 (18) :3192-3198

← 1 2 3 →