Migratory insertion of [B(C6F5)2] into C-H bonds:: CO promoted transfer of the boryl fragment

被引：9

作者：

Aldridge, Simon

Kays , Deborah L.

Al-Fawaz, Amal

Jones, Kevin M.

Horton, Peter N.

Hursthouse, Michael B.

Harrington, Ross W.

Clegg, William

机构：

[1] Cardiff Sch Chem, Ctr Fundamental & Appl Main Grp, Cardiff CF10 3AT, Wales

[2] Univ Southampton, Sch Chem, Natl Crystallog Serv, EPSRC, Southampton SO17 1BJ, Hants, England

[3] Univ Newcastle, Sch Nat Sci Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 24期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1039/b604141h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of (eta(5)-C5H5)Fe(CO)(2)B(C6F5)(2) with CO has been shown to proceed via ligand substitution at the metal with accompanying transfer of the boryl fragment ( via C - H insertion) to the Cp ring, thereby generating the zwitterion [eta(5)-C5H4B(C6F5)(2)H]Fe(CO)(3) in quantitative yield.

引用

页码：2578 / 2580

页数：3

共 53 条

[51] Theoretical investigation on functionalization of alkanes by a rhodium complex catalyst [J].