Methanolysis of seed oils in flowing supercritical carbon dioxide

被引：71

作者：

Jackson, MA

King, JW

机构：

[1] Food Quality and Safety Research, NCAUR, USDA, Peoria

[2] NCAUR, Peoria, IL 61604

来源：

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY | 1996年 / 73卷 / 03期

关键词：

fatty acid methyl esters; immobilized lipase; lipase; methanolysis; supercritical carbon dioxide;

D O I：

10.1007/BF02523430

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The direct methanolysis of triglycerides in flowing supercritical carbon dioxide by an immobilized lipase is described. The reaction system consists of two syringe pumps for substrate addition and another two syringe pumps for delivering CO2 at 24.1 MPa. Corn oil is pumped into the carbon dioxide stream at a rate of 4 mu L/min, and methanol is pumped at 5 mu L/min to yield fatty acid methyl esters (FAME) at >98% conversion. Direct methanolysis of soy flakes gives FAME at similar yields. This combined extraction/reaction is performed at 17.2 MPa and 50 degrees C. The fatty acid profiles obtained for these seed oils matches those obtained by classical chemical synthesis.

引用

页码：353 / 356

页数：4

共 33 条

[1]

AALTONEN O, 1991, CHEMTECH, V21, P240

[2]

*AM OIL CHEM SOC, 1969, OFF METH REC PRACT A

[3]

BERG BE, 1993, HRC-J HIGH RES CHROM, V16, P358

[4] ENANTIOSELECTIVITY AND REACTIVITY OF IMMOBILIZED LIPASE IN SUPERCRITICAL CARBON-DIOXIDE [J].

CERNIA, E ;

PALOCCI, C ;

GASPARRINI, F ;

MISITI, D ;

FAGNANO, N .

JOURNAL OF MOLECULAR CATALYSIS, 1994, 89 (1-2) :L11-L18

[5]

CHI YM, 1988, AGR BIOL CHEM TOKYO, V52, P1541

[6] ENZYMATIC-SYNTHESIS OF GERANYL ACETATE IN N-HEXANE WITH CANDIDA-ANTARCTICA LIPASES [J].

CLAON, PA ;

AKOH, CC .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1994, 71 (06) :575-578

[7]

CLIFFORD AA, 1994, NATO ADV SCI INST SE, V273, P449

[8] ENZYMATIC CATALYSIS IN MONOPHASIC ORGANIC-SOLVENTS [J].

DORDICK, JS .

ENZYME AND MICROBIAL TECHNOLOGY, 1989, 11 (04) :194-211

[9]

DUMONT T, 1992, BIOTECHNOL BIOENG, V39, P329

[10]

FARRIS RD, 1979, J AM OIL CHEM SOC, V56, P770

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