Synthesis and redox properties of bis-ferrocenylethynyl derivatives of bis(dimethylphosphinoethane)manganese

被引：5

作者：

Belen'kaya, AG ^{[1
]}

Dolgushin, FM ^{[1
]}

Peterleitner, MG ^{[1
]}

Petrovskii, PV ^{[1
]}

Krivykh, VV ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2002年 / 51卷 / 01期

关键词：

Mn-II and Mn-III paramagnetic complexes; ethynylferrocene; redox reactions; cyclic voltammetry; IR; H-1; NMR; and ESR spectra; X-ray diffraction analysis;

D O I：

10.1023/A:1015042604281

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Paramagnetic Mn(11)and Mn-111 complexes containing two ferrocenylethynyl ligands were synthesized. Their redox reactions were studied by cyclic voltammetry and chemical methods. The structures of the resulting compounds were determined by IR, H-1 NMR, and ESR spectroscopy. The structure of the complex [(FcC=C)(2)Mn(dmpe)(2)]+PF6- was established by X-ray diffraction analysis.

引用

页码：170 / 174

页数：5

共 14 条

[1]

[Anonymous], 1997, SHELXTL 97 V5 10

[2]

*BRUX AXS INC, 1998, SMART V5 051 SAINT V

[3]

COLBERT CB, 1997, J CHEM SOC DA, P99

[4]

DOISNEAU G, 1992, J ORGANOMET CHEM, V425, P113, DOI 10.1016/0022-328X(92)80026-T

[5]

GIROLAMI GS, 1985, J AM CHEM SOC, V107, P1339

[6] TERTIARY PHOSPHINE ADDUCTS OF MANGANESE(II) DICYCLOPENTADIENIDE - MAGNETIC STUDIES AND STRUCTURAL CHARACTERIZATION OF TILTED CYCLOPENTADIENYL RINGS [J].

HOWARD, CG ;

GIROLAMI, GS ;

WILKINSON, G ;

THORNTONPETT, M ;

HURSTHOUSE, MB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (07) :2033-2040

[7] Synthesis of a ferrocenyl-capped ruthenium(II) bis(acetylide) complex: A model for organometallic molecular wires [J].

Jones, ND ;

Wolf, MO ;

Giaquinta, DM .

ORGANOMETALLICS, 1997, 16 (07) :1352-1354

[8] Stable paramagnetic bis(alkynyl) manganese complexes [J].

Krivykh, VV ;

Eremenko, IL ;

Veghini, D ;

Petrunenko, IA ;

Pountney, DL ;

Unseld, D ;

Berke, H .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 511 (1-2) :111-114

[9]

La Mar G. N., 1973, NMR PARAMAGNETIC MOL

[10] Mono- and bis-alkynyl ruthenium(II) complexes containing the ferrocenyl moiety;: crystal structure of trans-[Ru(CCC5H4FeC5H5)2(Ph2PCH2CH2PPh2)2] and electrochemical studies [J].

Lebreton, C ;

Touchard, D ;

Le Pichon, L ;

Daridor, A ;

Toupet, L ;

Dixneuf, PH .

INORGANICA CHIMICA ACTA, 1998, 272 (1-2) :188-196

← 1 2 →