Polymer-Supported and Free-Standing Metal-Organic Framework Membrane

被引：88

作者：

Ben, Teng ^{[2
]}

Lu, Chunjing ^{[1
]}

Pei, Cuiying ^{[1
]}

Xu, Shixian ^{[1
]}

Qiu, Shilun ^{[1
]}

机构：

[1] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China

[2] Jilin Univ, Dept Chem, Changchun 130012, Peoples R China

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 33期

基金：

中国国家自然科学基金;

关键词：

gas separation; membranes; metal-organic frameworks; microporous materials; polymers; MOLECULAR-SIEVE MEMBRANE; LIQUID-PHASE EPITAXY; SORPTION PROPERTIES; HIGH PERMEABILITY; ALPHA-ALUMINA; SEPARATION; HYDROGEN; ADSORPTION; SELECTIVITY; CU-3(BTC)(2);

D O I：

10.1002/chem.201201574

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thrive on a polymer: A polymer-supported method is developed and used to prepare well-intergrown and free-standing metal-organic framework (MOF) membranes. By using this method, a stainless steel net/PMMA-PMAA-supported HKUST-1 membrane was fabricated and applied in gas separation. Results indicated that such a membrane has a high separation factor to H 2/N 2, H 2/CH 4, H 2/CO 2 gas mixtures (see figure). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10250 / 10253

页数：4

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