First example of a dumbbell-like architecture containing M3L2 cages and terephthalate anions

被引：70

作者：

Fan, J

Sun, WY ^{[1
]}

Okamura, T

Xie, J

Tang, WX

Ueyama, N

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[2] Osaka Univ, Grad Sch Sci, Dept Macromol Sci, Osaka 5600043, Japan

来源：

NEW JOURNAL OF CHEMISTRY | 2002年 / 26卷 / 02期

关键词：

D O I：

10.1039/b109141g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel complex [Ag-3(titmb)(2)](2)[1,4-C6H4(COO)(2)](3).23 H2O [titmb = 1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene] contains two M3L2 cages and three terephthalate anions, one of which is embedded in the two cages to form a dumbbell-like architecture and shows photoluminescence in the solid state when the titmb reacts with [Ag(NH3)(2)]NO3, an individual M3L2 cage [Ag-3(titmb)(2)][NO3](3).5 H2O without luminescent properties was obtained.

引用

页码：199 / 201

页数：3

共 26 条

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