CRYSTAL-STRUCTURES OF SILVER(I) AND THALLIUM(I) COMPLEXES OF TRIS[3-(2-PYRIDYL)-PYRAZOL-1-YL]BORATE - ENCAPSULATION OF EITHER A SINGLE THALLIUM(I) ION OR TRINUCLEAR SILVER(I) CLUSTER BY A HEXADENTATE PODAND

被引：63

作者：

AMOROSO, AJ ^{[1
]}

JEFFERY, JC ^{[1
]}

JONES, PL ^{[1
]}

MCCLEVERTY, JA ^{[1
]}

PSILLAKIS, E ^{[1
]}

WARD, MD ^{[1
]}

机构：

[1] UNIV BRISTOL,SCH CHEM,BRISTOL BS8 1TS,AVON,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 11期

关键词：

D O I：

10.1039/c39950001175

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title ligand (L(-)) forms a 1:1 complex [TIL] in which the Tl-I ion lies within the hexadentate cavity, coordinated strongly by the pyrazolyl N atoms but only very weakly by the pyridyl N atoms; in contrast the 3:2 complex [Ag(3)L(2)][ClO4] contains a triangular {Ag-3}(3)+ cluster core within the cavity of each ligand which accommodates the larger guest by increasing the apical N-B-N angles.

引用

页码：1175 / 1176

页数：2

共 13 条

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