Environmentally Benign Contemporary Friedel-Crafts Chemistry by Solid Acids

被引：41

作者：

Dasgupta, Sujaya ^{[1
]}

Torok, Bela ^{[1
]}

机构：

[1] Univ Massachusetts, Dept Chem, Boston, MA 02125 USA

来源：

CURRENT ORGANIC SYNTHESIS | 2008年 / 5卷 / 04期

关键词：

Friedel-Crafts; alkylation; acylation; solid acid; zeolite; montmorillonite; sulfonic acid resin; heteropolyacid;

D O I：

10.2174/157017908786241572

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Recent advances in the development of environmentally benign solid acid-catalyzed Friedel-Crafts reactions are reviewed. The work includes two main chapters, alkylations and acylations. The data are summarized based on the chemical nature of the reagents used, such as alkenes, alkyl halides and alcohols/ethers in alkylation, while activated carboxylic acid derivatives and carboxylic acids in acylation. Special topics in both major chapters, such as hydroxyalkylation, cyclialkylation, cycliacylation and rearrangements are also discussed.

引用

页码：321 / 342

页数：22

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