Synthesis and structure of bis(methylaluminium center dot NCCH3) p-tert-butylcalix[4]arene

被引：15

作者：

Gibson, VC ^{[1
]}

Redshaw, C ^{[1
]}

Clegg, W ^{[1
]}

Elsegood, MRJ ^{[1
]}

机构：

[1] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

来源：

POLYHEDRON | 1997年 / 16卷 / 24期

关键词：

partial cone conformation; X-ray crystallography; metallocalix[4]arenes;

D O I：

10.1016/S0277-5387(97)00234-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of p-tert-butylcalix[4]areneH(4) with AlMe3 in toluene at elevated temperature affords after work-up the complex {[MeAl(NCMe)](2)(p-tert-butylcalix[4]arene)}, which adopts a flattened partial cone conformation as characterized by X-ray crystallography. (C) 1997 Elsevier Science Ltd.

引用

页码：4385 / 4387

页数：3

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