Hydrogen production from solid sodium borohydride

被引：58

作者：

Gislon, P. ^{[1
]}

Monteleone, G. ^{[1
]}

Prosini, P. P. ^{[1
]}

机构：

[1] ENEA CR Casaccia, I-00123 Rome, Italy

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2009年 / 34卷 / 02期

关键词：

Hydrogen storage; Chemical hydrides; Sodium borohydride; GENERATION; STORAGE; HYDROLYSIS;

D O I：

10.1016/j.ijhydene.2008.09.105

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A system for a controlled production of hydrogen from solid NaBH4 has been designed and built. Cartridges of catalysed or non-catalysed NaBH4 in powder form are fed by water or catalyst solution into a reactor; the reaction is started and tuned by controlling the input water (or water/catalyst solution) flow. We designed, built and tested different reactor layouts and geometries. Tests have been carried out in order to monitor operative parameters (i.e., water flow, reactor temperature) and to evaluate their influence on hydrolysis performance. The facility allows hydrogen flow in the 5-30 L/h range for several hours. The paper reports on the experimental runs and on the main achieved goals. (C) 2008 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.

引用

页码：929 / 937

页数：9

共 20 条

[1] Hydrogen desorption and adsorption measurements on graphite nanofibers [J].