Synthesis and characterization of [(RuCl2)-Cl-III(TPA)]+(TPA equals tris(2-pyridylmethyl)amine) and its reactivity toward alkane functionalization

被引:50
作者
Kojima, T
机构
关键词
D O I
10.1246/cl.1996.121
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new ruthenium(III) monomer complex having a tripodal ligand TPA was synthesized and characterized by X-ray crystallography and cyclic voltammetry. The title compound was revealed to catalyze alkane functionalization with m-chloroperbenzoic acid.
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页码:121 / 122
页数:2
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共 12 条
[1]   A NOVEL MONOOXORUTHENIUM(V) COMPLEX CONTAINING A POLYDENTATE PYRIDYL AMINE LIGAND - SYNTHESES, REACTIVITIES, AND X-RAY CRYSTAL-STRUCTURE OF [RUIII(N4O)(H2O)](CLO4)2 [J].
CHE, CM ;
YAM, VWW ;
MAK, TCW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (06) :2284-2291
[2]   STRUCTURAL VARIATIONS INDUCED BY CHANGES IN OXIDATION-STATE AND THEIR ROLE IN ELECTRON-TRANSFER - CRYSTAL AND MOLECULAR-STRUCTURES OF CIS-[RU(BPY)2CL2].3.5H2O AND CIS-[RU(BPY)2CL2]CL.2H2O [J].
EGGLESTON, DS ;
GOLDSBY, KA ;
HODGSON, DJ ;
MEYER, TJ .
INORGANIC CHEMISTRY, 1985, 24 (26) :4573-4580
[3]  
GOLDSTEIN AS, 1993, J AM CHEM SOC, V115, P6450
[4]   AEROBIC EPOXIDATION OF OLEFINS WITH RUTHENIUM PORPHYRIN CATALYSTS [J].
GROVES, JT ;
QUINN, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (20) :5790-5792
[5]   ALKANE FUNCTIONALIZATION AT NONHEME IRON CENTERS - STOICHIOMETRIC TRANSFER OF METAL-BOUND LIGANDS TO ALKANE [J].
KOJIMA, T ;
LEISING, RA ;
YAN, SP ;
QUE, L .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (24) :11328-11335
[6]  
KOJIMA T, UNPUB
[7]   A TRANSIENT INTERMEDIATE OF THE METHANE MONOOXYGENASE CATALYTIC CYCLE CONTAINING AN FE(IV)FE(IV) CLUSTER [J].
LEE, SK ;
FOX, BG ;
FROLAND, WA ;
LIPSCOMB, JD ;
MUNCK, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (14) :6450-6451
[8]   ALKANE FUNCTIONALIZATION AT (MU-OXO)DIIRON(III) CENTERS [J].
LEISING, RA ;
KIM, JH ;
PEREZ, MA ;
QUE, L .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (21) :9524-9530
[9]   CHARACTERIZATION OF A DIIRON(III) PEROXO INTERMEDIATE IN THE REACTION CYCLE OF METHANE MONOOXYGENASE HYDROXYLASE FROM METHYLOCOCCUS-CAPSULATUS (BATH) [J].
LIU, KE ;
VALENTINE, AM ;
QIU, D ;
EDMONDSON, DE ;
APPELMAN, EH ;
SPIRO, TG ;
LIPPARD, SJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (17) :4997-4998
[10]   RUTHENIUM-CATALYZED CYTOCHROME-P-450 TYPE OXIDATION OF ALKANES WITH ALKYL HYDROPEROXIDES [J].
MURAHASHI, S ;
ODA, Y ;
NAOTA, T ;
KUWABARA, T .
TETRAHEDRON LETTERS, 1993, 34 (08) :1299-1302