Alloy corrosion

被引:144
作者
Newman, RC
Corcoran, SG
Erlebacher, J
Aziz, MJ
Sieradzki, K
机构
关键词
D O I
10.1557/S0883769400052660
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Alloy corrosion is a field of scientific study that combines electrochemical kinetics with aspects of the morphological evolution of surfaces. The basic alloy corrosion process is de-alloying, where a significant difference in the equilibrium metal/metal-ion electrode potentials for two metals occurs. In alloy systems where the ambient temperature corresponds to a small fraction of the homologous melting temperature, site-percolation thresholds set a lower bound on the parting limit. The parting limit represents the critical content of reactive alloy components that is required to allow de-alloying at an arbitrarily high anodic potential. Another field of alloy corrosion is passivation, where sharp compositional threshold behavior is observed.
引用
收藏
页码:24 / 28
页数:5
相关论文
共 27 条
  • [11] A MICRO-MORPHOLOGICAL STUDY OF THE DISSOLUTION OF SILVER-GOLD ALLOYS IN NITRIC-ACID
    FORTY, AJ
    DURKIN, P
    [J]. PHILOSOPHICAL MAGAZINE A-PHYSICS OF CONDENSED MATTER STRUCTURE DEFECTS AND MECHANICAL PROPERTIES, 1980, 42 (03): : 295 - 318
  • [12] CORROSION MICRO-MORPHOLOGY OF NOBLE-METAL ALLOYS AND DEPLETION GILDING
    FORTY, AJ
    [J]. NATURE, 1979, 282 (5739) : 597 - 598
  • [13] A POSSIBLE MODEL FOR CORROSION PITTING AND TUNNELLING IN NOBLE-METAL ALLOYS
    FORTY, AJ
    ROWLANDS, G
    [J]. PHILOSOPHICAL MAGAZINE A-PHYSICS OF CONDENSED MATTER STRUCTURE DEFECTS AND MECHANICAL PROPERTIES, 1981, 43 (01): : 171 - 188
  • [14] FORTY AJ, 1991, C FRANK 80 BIRTHDAY, P164
  • [15] PASSIVATION THRESHOLDS IN IRON-CHROMIUM ALLOYS PREPARED BY ION-BEAM SPUTTERING
    FUJIMOTO, S
    NEWMAN, RC
    SMITH, GS
    KAYE, SP
    KHEYRANDISH, H
    COLLIGON, JS
    [J]. CORROSION SCIENCE, 1993, 35 (1-4) : 51 - 55
  • [16] Jusys Z, 1998, ELECTROCHEM SOLID ST, V1, P74
  • [17] KELLY RG, 1993, AM SOC TEST MATER, V1188, P94, DOI 10.1520/STP18065S
  • [18] PRE-COLUMBIAN SURFACE METALLURGY
    LECHTMAN, H
    [J]. SCIENTIFIC AMERICAN, 1984, 250 (06) : 56 - 63
  • [19] The theory of the resistance limits in mixed crystals
    Masinc, G
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1921, 118 (04): : 293 - 308
  • [20] INSITU SCANNING TUNNELING MICROSCOPY OF CORROSION OF SILVER-GOLD ALLOYS
    OPPENHEIM, IC
    TREVOR, DJ
    CHIDSEY, CED
    TREVOR, PL
    SIERADZKI, K
    [J]. SCIENCE, 1991, 254 (5032) : 687 - 689