Catalysis in capillaries by Pd thin films using microwave-assisted continuous-flow organic synthesis (MACOS)

被引：148

作者：

Shore, G ^{[1
]}

Morin, S ^{[1
]}

Organ, MG ^{[1
]}

机构：

[1] York Univ, Dept Chem, N York, ON M3J 1P3, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 17期

关键词：

cross-coupling; microwaves; palladium; synthetic methods; thin films;

D O I：

10.1002/anie.200503600

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Finally ... metal in a microwave! Thin films of Pd black deposited onto the inner surface of microcapillaries are efficient for metal-catalyzed transformations under flow conditions including the Suzuki-Miyama and Heck couplings. The reaction mixture is flowed through these miniature capillaries while being microwaved, and conversion times are on the order of seconds. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2761 / 2766

页数：6

共 36 条

[31] Microwave-assisted polymer-supported combinatorial synthesis [J].