A High-Performing Solution-Processed Small Molecule: Perylene Diimide Bulk Heterojunction Solar Cell

被引：249

作者：

Sharenko, Alexander ^{[1
,2
]}

Proctor, Christopher M. ^{[1
,2
]}

van der Poll, Thomas S. ^{[1
,3
]}

Henson, Zachary B. ^{[1
,3
]}

Thuc-Quyen Nguyen ^{[1
,3
]}

Bazan, Guillermo C. ^{[1
,2
,3
]}

机构：

[1] Univ Calif Santa Barbara, Ctr Polymers & Organ Solids, Santa Barbara, CA 93106 USA

[2] Univ Calif Santa Barbara, Dept Mat, Santa Barbara, CA 93106 USA

[3] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

来源：

ADVANCED MATERIALS | 2013年 / 25卷 / 32期

基金：

美国国家科学基金会;

关键词：

bulk heterojunction solar cells; small molecules; perylene diimide; non-fullerene acceptors; RECOMBINATION; TRANSPORT; BLENDS;

D O I：

10.1002/adma.201301167

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By combining the molecular donor p-DTS(FBTTh2)2 with a readily produced perylene diimide acceptor we are able to achieve a power conversion efficiency of 3.0%, making this one of the most efficient non-fullerene organic solar cells to date. The reduced power conversion efficiency of the present system compared to the use of phenyl-C 71-butyric acid methyl ester as an electron acceptor is shown to primarily be related to a significant reduction in the internal quantum efficiency. These results indicate the potential of small-molecule:non-fullerene bulk-heterojunction organic photovoltaics. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4403 / 4406

页数：4

共 32 条

[1] On the Field Dependence of Free Charge Carrier Generation and Recombination in Blends of PCPDTBT/PC70BM: Influence of Solvent Additives [J].

Albrecht, Steve ;

Schindler, Wolfram ;

Kurpiers, Jona ;

Kniepert, Juliane ;

Blakesley, James C. ;

Dumsch, Ines ;

Allard, Sybille ;

Fostiropoulos, Konstantinos ;

Scherf, Ullrich ;

Neher, Dieter .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2012, 3 (05) :640-645

[2]

Anctil A., 2010, 2010 35 IEEE PHOT SP

[3] Material and Energy Intensity of Fullerene Production [J].

Anctil, Annick ;

Babbitt, Callie W. ;

Raffaelle, Ryne P. ;

Landi, Brian J. .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2011, 45 (06) :2353-2359

[4]

[Anonymous], ADV FUNCT MAT

[5] The Importance of Fullerene Percolation in the Mixed Regions of Polymer-Fullerene Bulk Heterojunction Solar Cells [J].

Bartelt, Jonathan A. ;

Beiley, Zach M. ;

Hoke, Eric T. ;

Mateker, William R. ;

Douglas, Jessica D. ;

Collins, Brian A. ;

Tumbleston, John R. ;

Graham, Kenneth R. ;

Amassian, Aram ;

Ade, Harald ;

Frechet, Jean M. J. ;

Toney, Michael F. ;

McGehee, Michael D. .

ADVANCED ENERGY MATERIALS, 2013, 3 (03) :364-374

[6] A New Approach for Probing the Mobility and Lifetime of Photogenerated Charge Carriers in Organic Solar Cells Under Real Operating Conditions [J].

Baumann, A. ;

Lorrmann, J. ;

Rauh, D. ;

Deibel, C. ;

Dyakonov, V. .

ADVANCED MATERIALS, 2012, 24 (32) :4381-4386

[7] Solution-Processed Organic Solar Cells with Power Conversion Efficiencies of 2.5% using Benzothiadiazole/Imide-Based Acceptors [J].

Bloking, Jason T. ;

Han, Xu ;

Higgs, Andrew T. ;

Kastrop, John P. ;

Pandey, Laxman ;

Norton, Joseph E. ;

Risko, Chad ;

Chen, Cynthia E. ;

Bredas, Jean-Luc ;

McGehee, Michael D. ;

Sellinger, Alan .

CHEMISTRY OF MATERIALS, 2011, 23 (24) :5484-5490

[8] Accounting for Interference, Scattering, and Electrode Absorption to Make Accurate Internal Quantum Efficiency Measurements in Organic and Other Thin Solar Cells [J].

Burkhard, George F. ;

Hoke, Eric T. ;

McGehee, Michael D. .

ADVANCED MATERIALS, 2010, 22 (30) :3293-+

[9] Organic thin film transistors based on N-alkyl perylene diimides:: Charge transport kinetics as a function of gate voltage and temperature [J].

Chesterfield, RJ ;

McKeen, JC ;

Newman, CR ;

Ewbank, PC ;

da Silva, DA ;

Brédas, JL ;

Miller, LL ;

Mann, KR ;

Frisbie, CD .

JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (50) :19281-19292

[10] Quantification of Geminate and Non-Geminate Recombination Losses within a Solution-Processed Small-Molecule Bulk Heterojunction Solar Cell [J].

Credgington, Dan ;

Jamieson, Fiona C. ;

Walker, Bright ;

Thuc-Quyen Nguyen ;

Durrant, James R. .

ADVANCED MATERIALS, 2012, 24 (16) :2135-2141

← 1 2 3 4 →