Dual-functional materials via CCTP and selective orthogonal thiol-Michael addition/epoxide ring opening reactions

被引：28

作者：

McEwan, Kayleigh A. ^{[1
]}

Slavin, Stacy ^{[1
]}

Tunnah, Edward ^{[1
]}

Haddleton, David M. ^{[1
]}

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

POLYMER CHEMISTRY | 2013年 / 4卷 / 08期

基金：

英国工程与自然科学研究理事会;

关键词：

CATALYTIC CHAIN TRANSFER; GLYCIDYL METHACRYLATE; POLYMER BRUSHES; COPOLYMER; ACRYLONITRILE; TEMPERATURE; COMBINATION;

D O I：

10.1039/c3py21104e

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(glycidyl methacrylate) (PGMA) has been synthesised by cobalt catalysed chain transfer polymerisation (CCTP) yielding, in one step, polymers with two points for post polymerisation functionalisation; the activated terminal vinyl bond and in chain epoxide groups. Epoxide ring-opening and a combination of thiol-Michael addition and epoxide ring-opening has been used for the post-functionalisation with amines and thiols to prepare a range of functional materials.

引用

页码：2608 / 2614

页数：7

共 37 条

[1] Surface Functionalization Methods To Enhance Bioconjugation in Metal-Labeled Polystyrene Particles [J].

Abderahman, Ahmed I. ;

Thickett, Stuart C. ;

Liang, Yi ;

Ornatsky, Olga ;

Baranov, Vladimir ;

Winnik, Mitchell A. .

MACROMOLECULES, 2011, 44 (12) :4801-4813

[2] Protein Microarrays Based on Polymer Brushes Prepared via Surface-Initiated Atom Transfer Radical Polymerization [J].

Barbey, Raphael ;

Kauffmann, Ekkehard ;

Ehrat, Markus ;

Klok, Harm-Anton .

BIOMACROMOLECULES, 2010, 11 (12) :3467-3479

[3] Room Temperature, Aqueous Post-Polymerization Modification of Glycidyl Methacrylate-Containing Polymer Brushes Prepared via Surface-Initiated Atom Transfer Radical Polymerization [J].

Barbey, Raphael ;

Klok, Harm-Anton .

LANGMUIR, 2010, 26 (23) :18219-18230

[4] Specific Features of Amination of Poly(Glycidyl Methacrylate) Chains Grafted onto Polypropylene Fibers [J].

Bondar', Yu. V. ;

Han, D. H. .

RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2012, 85 (02) :272-276

[5]

Clayden J., 2001, ORGANIC CHEM

[6] Synthesis and characterization of glycidyl methacrylate/butyl acrylate copolymers obtained at a low temperature by atom transfer radical polymerization [J].

De La Fuente, JL ;

Cañamero, PF ;

Fernández-García, M .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2006, 44 (06) :1807-1816

[7]

de Numours E. I. Dupont, 1952, GB Patent, Patent No. [740 720, 740720]

[8]

De S., 2012, CHEM COMMUN, V48

[9] A general synthetic strategy to prepare poly(ethylene glycol)-based multifunctional copolymers [J].

De, Swati ;

Stelzer, Carol ;

Khan, Anzar .

POLYMER CHEMISTRY, 2012, 3 (09) :2342-2345

[10] Synthesis and Characterization of Thermally and Chemically Gelling Injectable Hydrogels for Tissue Engineering [J].

Ekenseair, Adam K. ;

Boere, Kristel W. M. ;

Tzouanas, Stephanie N. ;

Vo, Tiffany N. ;

Kasper, F. Kurtis ;

Mikos, Antonios G. .

BIOMACROMOLECULES, 2012, 13 (06) :1908-1915

← 1 2 3 4 →