Low-power decoupling in fast magic-angle spinning NMR

被引:103
作者
Ernst, M [1 ]
Samoson, A
Meier, BH
机构
[1] Swiss Fed Inst Technol, CH-8093 Zurich, Switzerland
[2] NICPB, EE-12618 Tallinn, Estonia
关键词
D O I
10.1016/S0009-2614(01)01115-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We investigate the possibility of a low-power rf-irradiation approach to heteronuclear spin decoupling in solid-state NMR under high-frequency magic-angle sample spinning. Decoupling is achieved by applying an rf-field with an amplitude corresponding to a precession frequency much lower than the spinning frequency. This leads to a reversal of the averaging processes compared to normal high-power continuous-wave decoupling. Such an approach becomes increasingly interesting with increasing MAS spinning frequency. In rigid solids, low-power decoupling becomes competitive above about 40 kHz MAS frequency. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:293 / 302
页数:10
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