A New Route to Acrylate Oils: Crosslinking and Properties of Acrylate Triglycerides from High Oleic Sunflower Oil

被引：59

作者：

de Espinosa, L. Montero ^{[1
]}

Ronda, J. C. ^{[1
]}

Galia, M. ^{[1
]}

Cadiz, V. ^{[1
]}

机构：

[1] Univ Rovira & Virgili, Dept Quim Analit & Quim Organ, Tarragona 43007, Spain

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2009年 / 47卷 / 04期

关键词：

acrylate; crosslinking; radical polymerization; renewable resources; triglyceride; SINGLET OXYGEN; POLYMERS; ACID; POLYMERIZATION; HYDROPEROXIDES; EPOXIDATION; ALKENES; ESTERS;

D O I：

10.1002/pola.23225

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Triglycerides with acrylate functionality were prepared from a new route that involves the singlet oxygen photooxygenation of high oleic sunflower oil and further reduction of the resulting hydroperoxide derivatives to a mixture of secondary allylic alcohols. These unsaturated alcohols can be further reduced to saturated alcohols. These two new hydroxyl-containing triglycerides were functionalized as acrylate esters and radically crosslinked in presence of different amounts of pentaerythritol tetraacrylate. The crosslinking reactions were followed by FTIR spectroscopy and the thermal properties of the final materials were evaluated. (C) 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 1159-1167, 2009

引用

页码：1159 / 1167

页数：9

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