Hydrothermal synthesis of indium tartrates:: Structures of the chiral polymer [In(L-TAR)3-H2O] • 0.5H2O containing the tartrate trianion, and a microporous hybrid solid [In(OH)(D/L-TAR)2-] • 2H2O

被引：24

作者：

Au-Yeung, Alex S. -F. ^{[1
]}

Sung, Herman H. -Y. ^{[1
]}

Cha, John A. K. ^{[1
]}

Siu, Alvin W. -H. ^{[1
]}

Chui, Stephen S. -Y. ^{[1
]}

Williams, Ian D. ^{[1
]}

机构：

[1] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 05期

关键词：

hydrothermal synthesis; indium; microporous solids; chiral polymers;

D O I：

10.1016/j.inoche.2006.01.017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrothermal reaction of indium hydroxide with L-tartaric acid or racemic D/L-tartaric acid at 110 degrees C for 3 days affords, respectively 1 [ln(L-TAR)H2O] center dot 0.5H(2)O which contains tartrate trianions and has a 2D structure, and 2 [In(OH)(D/L-TAR)] center dot 2H(2)O, with a microporous 3D framework that undergoes phase transformation at ca. 150 degrees C. (C) 2006 Elsevier B.V. All rights reserved.

引用

页码：507 / 511

页数：5

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