Two novel inorganic-organic hybrid frameworks based on InIII-BTC and InIII-BTEC

被引：67

作者：

Lin, ZZ ^{[1
]}

Jiang, FL ^{[1
]}

Chen, L ^{[1
]}

Yuan, DQ ^{[1
]}

Zhou, YF ^{[1
]}

Hong, MC ^{[1
]}

机构：

[1] Chinese Acad Sci, Grad Sch, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Fuzhou, Peoples R China

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2005年 / 01期

关键词：

indium(III); benzenemulticarboxylate;

D O I：

10.1002/ejic.200400591

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrothermal reactions of InCl3 with 1,3,5-benzenetricarboxylic acid (H3BTC) or pyromellitic dianhydride produced [ln(2)(BTC)(2)(H2O)(2)](n).2nH(2)O (1) and [ln(2)(H2BTEC)(2)(OH)(2)](n).2nH(2)O (2), respectively (H4BTEC = 1,2,4,5-benzenetetracarboxylic acid). The structure of 1 is a 2D double-layer network, while that of 2 is a 3D framework constructed from chains of corner-linked octahedra. Intense greenish-blue emissions at 494 nm (lambda(ex) = 325 nm) for 1 and 489 nm (lambda(ex) 337 nm) for 2 were observed in the solid state. (C) Wiley-VCH Verlag GmbH Co.

引用

页码：77 / 81

页数：5

共 31 条

[1] Synthesis, structure, and magnetic properties of two new vanadocarboxylates with three-dimensional hybrid frameworks [J].

Barthelet, K ;

Riou, D ;

Nogues, M ;

Férey, G .

INORGANIC CHEMISTRY, 2003, 42 (05) :1739-1743

[2]

Bellamy LJNY., 2013, INFRA RED SPECTRA CO

[3] BOND-VALENCE PARAMETERS FOR SOLIDS [J].

BRESE, NE ;

OKEEFFE, M .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1991, 47 :192-197

[4] Syntheses and characterizations of three-dimensional channel-like polymeric lanthanide complexes constructed by 1,2,4,5-benzenetetracarboxylic acid [J].

Cao, R ;

Sun, DF ;

Liang, YC ;

Hong, MC ;

Tatsumi, K ;

Shi, Q .

INORGANIC CHEMISTRY, 2002, 41 (08) :2087-2094

[5] Photoluminescent metal-organic polymer constructed from trimetallic clusters and mixed carboxylates [J].

Chen, W ;

Wang, JY ;

Chen, C ;

Yue, Q ;

Yuan, HM ;

Chen, JS ;

Wang, SN .

INORGANIC CHEMISTRY, 2003, 42 (04) :944-946

[6] Coordination polymers composed of copper(II), trimesic acid, and imidazole: 3D architecture stabilized by hydrogen bonding [J].

Cheng, DP ;

Khan, MA ;

Houser, RP .

INORGANIC CHEMISTRY, 2001, 40 (27) :6858-+

[7] Self-assembly of molecular brick wall and molecular honeycomb from nickel(II) macrocycle and 1,3,5-benzenetricarboxylate: Guest-dependent host structures [J].

Choi, HJ ;

Suh, MP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (41) :10622-10628

[8] Synthesis and structural characterization of {[Fe(OH)(H2bta)](H2O)}n (3-D) (H4bta = benzenetetracarboxylic acid) [J].

Chu, DQ ;

Pan, CL ;

Wang, LM ;

Xu, JQ .

MENDELEEV COMMUNICATIONS, 2002, (05) :207-209

[9] Synthesis, structure, and fluorescence of the novel cadmium(II)-trimesate coordination polymers with different coordination architectures [J].

Dai, JC ;

Wu, XT ;

Fu, ZY ;

Cui, CP ;

Hu, SM ;

Du, WX ;

Wu, LM ;

Zhang, HH ;

Sun, RO .

INORGANIC CHEMISTRY, 2002, 41 (06) :1391-1396

[10] Synthesis and crystal structure of two new rare earth trimesate complexes:: ErTMA(H2O)5•3.5H2O and YTMA(H2O)6 [J].

Daiguebonne, C ;

Guilloa, O ;

Gérault, Y ;

Lecerf, A ;

Boubekeur, K .

INORGANICA CHIMICA ACTA, 1999, 284 (01) :139-145

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