Fast synthesis of carbon microspheres via a microwave-assisted reaction for sodium ion batteries

被引:143
作者
Chen, Taiqiang [1 ]
Pan, Likun [1 ]
Lu, Ting [1 ]
Fu, Conglong [1 ]
Chua, Daniel H. C. [2 ]
Sun, Zhuo [1 ]
机构
[1] E China Normal Univ, Dept Phys, Minist Educ, Engn Res Ctr Nanophoton & Adv Instrument, Shanghai 200062, Peoples R China
[2] Natl Univ Singapore, Dept Mat Sci & Engn, Singapore 117574, Singapore
基金
中国国家自然科学基金;
关键词
REDUCED GRAPHENE OXIDE; LITHIUM-ION; ANODE MATERIAL; ELECTROCHEMICAL INSERTION; RATE CAPABILITY; ENERGY-STORAGE; RESORCINOL-FORMALDEHYDE; NANOTUBE COMPOSITES; ELECTRODE MATERIALS; NEGATIVE ELECTRODE;
D O I
10.1039/c3ta14037g
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A fast microwave-assisted approach was developed to fabricate carbon microspheres (CSs) using sucrose as the precursor in a microwave system. After thermal treatment at 300, 500, 700 and 1000 degrees C, the CSs were used as anode materials for sodium ion batteries (SIBs). The results show that CSs treated at 500 degrees C exhibit a maximum capacity of 183 mA h g(-1) at a current density of 30 mA g(-1) after 50 cycles, and even at a high current density of 1000 mA g(-1) a capacity of 83 mA h g(-1) is maintained. The high capacity, good cycling stability and excellent rate performance of CSs, due to their unique spherical structure, make them a promising candidate for anode materials for SIBs.
引用
收藏
页码:1263 / 1267
页数:5
相关论文
共 59 条
[1]   Carbon microspheres obtained from resorcinol-formaldehyde as high-capacity electrodes for sodium-ion batteries [J].
Alcántara, R ;
Lavela, P ;
Ortiz, GF ;
Tirado, JL .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2005, 8 (04) :A222-A225
[2]   Carbon black:: a promising electrode material for sodium-ion batteries [J].
Alcántara, R ;
Jiménez-Mateos, JM ;
Lavela, P ;
Tirado, JL .
ELECTROCHEMISTRY COMMUNICATIONS, 2001, 3 (11) :639-642
[3]   Negative electrodes for lithium- and sodium-ion batteries obtained by heat-treatment of petroleum cokes below 1000°C [J].
Alcántara, R ;
Mateos, JMJ ;
Tirado, JL .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (02) :A201-A205
[4]   Characterisation of mesocarbon microbeads (MCMB) as active electrode material in lithium and sodium cells [J].
Alcántara, R ;
Madrigal, FJF ;
Lavela, P ;
Tirado, JL ;
Mateos, JMJ ;
de Salazar, CG ;
Stoyanova, R ;
Zhecheva, E .
CARBON, 2000, 38 (07) :1031-1041
[5]   Structural Characterization of Hydrothermal Carbon Spheres by Advanced Solid-State MAS 13C NMR Investigations [J].
Baccile, Niki ;
Laurent, Guillaume ;
Babonneau, Florence ;
Fayon, Franck ;
Titirici, Maria-Magdalena ;
Antonietti, Markus .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (22) :9644-9654
[6]   Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applications [J].
Cao, Yuliang ;
Xiao, Lifen ;
Sushko, Maria L. ;
Wang, Wei ;
Schwenzer, Birgit ;
Xiao, Jie ;
Nie, Zimin ;
Saraf, Laxmikant V. ;
Yang, Zhengguo ;
Liu, Jun .
NANO LETTERS, 2012, 12 (07) :3783-3787
[7]   Microwave-assisted synthesis of reduced graphene oxide-carbon nanotube composites as negative electrode materials for lithium ion batteries [J].
Chen, Taiqiang ;
Pan, Likun ;
Yu, Kai ;
Sun, Zhuo .
SOLID STATE IONICS, 2012, 229 :9-13
[8]   One-step synthesis of SnO2-reduced graphene oxide-carbon nanotube composites via microwave assistance for lithium ion batteries [J].
Chen, Taiqiang ;
Pan, Likun ;
Liu, Xinjiuan ;
Yu, Kai ;
Sun, Zhuo .
RSC ADVANCES, 2012, 2 (31) :11719-11724
[9]   Water-soluble binders for MCMB carbon anodes for lithium-ion batteries [J].
Courtel, Fabrice M. ;
Niketic, Svetlana ;
Duguay, Dominique ;
Abu-Lebdeh, Yaser ;
Davidson, Isobel J. .
JOURNAL OF POWER SOURCES, 2011, 196 (04) :2128-2134
[10]   ELECTROCHEMICAL INSERTION OF SODIUM INTO CARBON [J].
DOEFF, MM ;
MA, YP ;
VISCO, SJ ;
DEJONGHE, LC .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1993, 140 (12) :L169-L170