Characterization of large-pore MCM-41 molecular sieves obtained via hydrothermal restructuring

被引:309
作者
Sayari, A
Liu, P
Kruk, M
Jaroniec, M
机构
[1] KENT STATE UNIV, DEPT CHEM, KENT, OH 44242 USA
[2] UNIV LAVAL, DEPT CHEM ENGN, ST FOY, PQ G1K 7P4, CANADA
[3] UNIV LAVAL, CERPIC, ST FOY, PQ G1K 7P4, CANADA
关键词
D O I
10.1021/cm970128o
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
MCM-41 periodic mesoporous silicates were synthesized using cetyltrimethylammonium bromide, and their pore sizes were tailored by postsynthesis hydrothermal treatment method of Khushalani et al., allowing us to obtain large-pore MCM-41 samples with a high degree of structural ordering. It was shown that the pore size enlargement was accompanied by a significant improvement of pore size uniformity, a gradual decrease of the specific surface area, and the pore wall thickening. After a certain upper limit of pore size (i.e., about 6.5 nm) was reached, a further hydrothermal treatment led to samples of diminished quality. The structural uniformity decreases dramatically, i.e., the pore size distribution becomes broader and a small but noticeable amount of micropores develops. Moreover, the appearance of pore blocking effects (as inferred from the irreversibility of nitrogen adsorption-desorption isotherms) indicates that the pore geometry deviates significantly from its initial cylindrical shape characteristic for MCM-41 materials. The current study confirmed previous findings that the hydrothermal restructuring method is a convenient way to synthesize high quality MCM-41 silicates with tailored pore sizes, but only up to 6.5 nm.
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页码:2499 / 2506
页数:8
相关论文
共 28 条
[1]  
*5057296 US, 1991, BECK JS
[2]   THE DETERMINATION OF PORE VOLUME AND AREA DISTRIBUTIONS IN POROUS SUBSTANCES .1. COMPUTATIONS FROM NITROGEN ISOTHERMS [J].
BARRETT, EP ;
JOYNER, LG ;
HALENDA, PP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (01) :373-380
[3]   A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].
BECK, JS ;
VARTULI, JC ;
ROTH, WJ ;
LEONOWICZ, ME ;
KRESGE, CT ;
SCHMITT, KD ;
CHU, CTW ;
OLSON, DH ;
SHEPPARD, EW ;
MCCULLEN, SB ;
HIGGINS, JB ;
SCHLENKER, JL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843
[4]   Adsorption of gases in multimolecular layers [J].
Brunauer, S ;
Emmett, PH ;
Teller, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 :309-319
[5]   Synthesis and characterization of inorganic gels in a lyotropic liquid crystal medium .2. Synthesis of silica gels in lyotropic crystal phases obtained from cationic surfactants [J].
Dabadie, T ;
Ayral, A ;
Guizard, C ;
Cot, L ;
Lacan, P .
JOURNAL OF MATERIALS CHEMISTRY, 1996, 6 (11) :1789-1794
[6]   UNUSUAL TYPE OF ADSORPTION-ISOTHERM DESCRIBING CAPILLARY CONDENSATION WITHOUT HYSTERESIS [J].
FRANKE, O ;
SCHULZEKLOFF, G ;
RATHOUSKY, J ;
STAREK, J ;
ZUKAL, A .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (09) :724-726
[7]  
GREGG SJ, 1982, ADSORPTION SURFACE
[8]   MESOSTRUCTURE DESIGN WITH GEMINI SURFACTANTS - SUPERCAGE FORMATION IN A 3-DIMENSIONAL HEXAGONAL ARRAY [J].
HUO, QS ;
LEON, R ;
PETROFF, PM ;
STUCKY, GD .
SCIENCE, 1995, 268 (5215) :1324-1327
[9]   ORGANIZATION OF ORGANIC-MOLECULES WITH INORGANIC MOLECULAR-SPECIES INTO NANOCOMPOSITE BIPHASE ARRAYS [J].
HUO, QS ;
MARGOLESE, DI ;
CIESLA, U ;
DEMUTH, DG ;
FENG, PY ;
GIER, TE ;
SIEGER, P ;
FIROUZI, A ;
CHMELKA, BF ;
SCHUTH, F ;
STUCKY, GD .
CHEMISTRY OF MATERIALS, 1994, 6 (08) :1176-1191
[10]   Surfactant control of phases in the synthesis of mesoporous silica-based materials [J].
Huo, QS ;
Margolese, DI ;
Stucky, GD .
CHEMISTRY OF MATERIALS, 1996, 8 (05) :1147-1160