Synthesis of Cyclic Carbonates from Epoxides and Carbon Dioxide by Using Organocatalysts

被引：518

作者：

Cokoja, Mirza ^{[1
,2
]}

Wilhelm, Michael E. ^{[1
,2
]}

Anthofer, Michael H. ^{[1
,2
]}

Herrmann, Wolfgang A. ^{[1
,2
]}

Kuehn, Fritz E. ^{[1
,2
]}

机构：

[1] Tech Univ Munich, Dept Chem, Chair Inorgan Chem Mol Catalysis, D-85747 Garching, Germany

[2] Tech Univ Munich, Catalysis Res Ctr, D-85747 Garching, Germany

来源：

CHEMSUSCHEM | 2015年 / 8卷 / 15期

关键词：

carbon dioxide; cyclic carbonates; epoxides; organocatalysis; sustainable chemistry; LINKED POLYMERIC NANOPARTICLES; FUNCTIONALIZED IONIC LIQUID; HIGHLY EFFICIENT SYNTHESIS; QUATERNARY AMMONIUM-SALT; ONE-STEP SYNTHESIS; CHEMICAL FIXATION; PROPYLENE CARBONATE; IMIDAZOLIUM BROMIDES; CATALYTIC-SYSTEM; HETEROGENEOUS CATALYST;

D O I：

10.1002/cssc.201500161

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

The synthesis of cyclic carbonates through coupling of carbon dioxide with epoxides is 100% atom economical and is already performed on an industrial scale. Its impact regarding the use of carbon dioxide as a renewable carbon source is expected to grow significantly in the near future, so that the development of efficient catalysts is of high interest in academia and industry. To improve the carbon footprint and sustainability of the cycloaddition reaction, the use of organocatalytic methods is a promising approach. Herein, available metal-free catalysts for the preparation of cyclic carbonates are described and elaborated concerning the overall sustainability of the process. Therefore, the required reaction conditions, as well as the activity of the catalysts and their reusability, are compared and evaluated. In addition to ammonium-, phosphonium-, or imidazolium- based single-component catalysts and their supported analogues, the growing field of research concerning dual catalysts are also discussed in detail.

引用

页码：2436 / 2454

页数：19

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