Manganese(III) acetate initiated oxidative free radical reaction between 1,4-naphthoquinones and ethyl nitroacetate

被引：47

作者：

Chuang, CP ^{[1
]}

Wu, YL ^{[1
]}

Jiang, MC ^{[1
]}

机构：

[1] Natl Cheng Kung Univ, Dept Chem, Tainan 70101, Taiwan

来源：

TETRAHEDRON | 1999年 / 55卷 / 37期

关键词：

D O I：

10.1016/S0040-4020(99)00646-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The manganese(III) initiated oxidative free radical reaction between 1,4-naphthquinones and ethyl nitroacetate is described. Nitromethyl radical 1 can be generated effectively from the oxidation of ethyl nitroacetate by manganese(III) acetate. Naphtho[2,3-d]isoxazole-4,9-diones, benzo[f]indole-4,9-diones and benzo[b]acridine-6, 11-diones were prepared effectively from readily available 1,4-naphthoquinones and ethyl nitroacetate. (C) 1999 Elsevier Science Ltd, All rights reserved.

引用

页码：11229 / 11236

页数：8

共 22 条

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