Manganese(III) acetate initiated oxidative free radical reaction between 1-anilino-1,4-naphthoquinones and diethyl malonate

被引：21

作者：

Chuang, CP

Wang, SF

机构：

[1] Department of Chemistry, National Cheng Kung University, Tainan

来源：

JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 1997年 / 44卷 / 03期

关键词：

D O I：

10.1002/jccs.199700042

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A free radical reaction between 2-anilino-1,4-naphthoquinones and diethyl malonate initiated by manganese (III) acetate is described. This reaction provides a novel method for the synthesis of 5,6,11,12-tetrahydro-6,11-dioxo-benzo[b]acridines. With a meta substituent on the anilino group, this reaction shows poor to high regioselectivity depending on the steric effect of the substituents on the anilino group and malonate.

引用

页码：271 / 277

页数：7

共 24 条

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