ULTRASOUND EFFECTS ON THE MN(III) - PROMOTED ADDITION OF AMIDOALKYL RADICALS TO OLEFINS

被引：18

作者：

BOSMAN, C ^{[1
]}

DANNIBALE, A ^{[1
]}

RESTA, S ^{[1
]}

TROGOLO, C ^{[1
]}

机构：

[1] UNIV ROMA LA SAPIENZA,CNR,CTR STUDIO CHIM SOSTANZE ORGAN NAT,DIPARTIMENTO CHIM,I-00185 ROME,ITALY

来源：

TETRAHEDRON | 1994年 / 50卷 / 48期

关键词：

D O I：

10.1016/S0040-4020(01)85692-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Amidoalkyl radicals, generated from amides by Mn(OAc)(3) in acetic acid react with phenyl substituted alkenes to generate five-membered lactones or lactams. Ultrasound at ambient temperature significantly accelerates these single electron transfer reactions even when compared with conventional conditions under reflux or simple mechanical stirring. In some cases sonication leads to unusual products.

引用

页码：13847 / 13856

页数：10

共 4 条

[1] LACTONIZATION OF OLEFINS MEDIATED BY MN(OAC)3 - A SONOCHEMICAL APPROACH [J].