Vanadocene-mediated ionization of water in the aqua species [H2O•B(C6F5)3]:: Structural characterization of the hydride and hydroxide complexes [CP2V(μ-OH)B(C6F5)3] and [CP2V(μ-OH)B(C6F5)3]

被引：14

作者：

Choukroun, R ^{[1
]}

Lorber, C ^{[1
]}

Vendier, L ^{[1
]}

Lepetit, C ^{[1
]}

机构：

[1] CNRS, UPR 8241, Chim Coordinat Lab, F-31077 Toulouse 04, France

来源：

ORGANOMETALLICS | 2006年 / 25卷 / 07期

关键词：

D O I：

10.1021/om050965x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Cp2V with B(C6F5)(3) in the presence of water leads to the hydride complex [Cp2V(mu-H)B(C6F5)(3)] (1) and the hydroxide complex [Cp2V(mu-OH)B(C6F5)(3)] (2), both of which have been characterized by, X-ray structure determinations. Both complexes are derived from the ionization of water in the presence of B(C6F5)(3).

引用

页码：1551 / 1553

页数：3

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